Because coffee grounds would actually make terrible aggregate, as complex organic and formerly alive compounds, there's a lot of potential for weird chemical breakdown that could harm the concrete or anything else in the concrete.
Char is pretty chemically stable, because carbon is very chemically stable.
Are post WW2 borders sacred? Is Crimea, transferred by Soviet Russia to the Ukraine in 1954, sacred? It's called international law. Yes it should be sacred. Nothing you say justifies by any means Putin's aggression and war crimes. Putin is a thug. He is a mob boss. Ukraine will join the EU. Ukraine will join NATA. Ukraine's economy and culture will flourish while Russia will be a pariah until Putin dies of old age and a respectable and honourable leader takes his place.