The article and paper don't mention it, but the thermal conductivity of single crystal diamond can be increased another 50% at room temperature by using pure carbon-12. The isotopic uniformity reduces scattering of phonons, which are what transports heat energy in diamond. For a very thin film like this the cost of using isotopically purified carbon shouldn't be that bad.
BTW, the thermal conductivity of C-12 diamond at cryogenic temperature is even higher, reaching something like 41000 W/m K at 104 K.
Isotopically purified silicon has also been considered due to its higher thermal conductivity, but the effect there at room temperature is not nearly as dramatic.
Weirdly, I read UV damage in C-12 diamond is reduced by a factor of 10 vs. natural diamond, I understand because this damage process is mediated by phonons. No relevance to the chip use case (unless UV damage in photolithography could be important?), but I found it interesting.
This is polycrystalline diamond, which probably scatters phonons anyway, so it seems naively like using a single isotope wouldn't help much. But that's definitely an interesting fact and I think you're right that it probably wouldn't add much expense when the amount of material is so small.
I'm not sure that's too dominant? The thermal conductivity reported is close to the natural diamond, so increasing the conductivity of the individual microcrystals could still be significant.
I joked about it last year[0], but before going for isotopically pure diamond they first have to make them single-crystal, the grain boundaries are worse than isotopic impurities.
BTW, the thermal conductivity of C-12 diamond at cryogenic temperature is even higher, reaching something like 41000 W/m K at 104 K.
Isotopically purified silicon has also been considered due to its higher thermal conductivity, but the effect there at room temperature is not nearly as dramatic.
Weirdly, I read UV damage in C-12 diamond is reduced by a factor of 10 vs. natural diamond, I understand because this damage process is mediated by phonons. No relevance to the chip use case (unless UV damage in photolithography could be important?), but I found it interesting.